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Study of catalytic processes for the production of hydrogen/syngas, ammonia and synthetic methane

Laboratorio n.

5

Study of catalytic processes for the production of hydrogen/syngas, ammonia and synthetic methane

Topic

CO2 conversion into alternative fuels using heterogeneous catalysis; conversion of by-products and bio-derivatives into environmentally friendly energy carriers; synthetic fuels; energetic treatment and qualification of biomasses; power to gas (methanation); green ammonia synthesis; production of hydrogen from fossil fuels and green ammonia.

4Y6A3020

The laboratory has facilities and equipment for the study of thermocatalytic and photocatalytic processes for the production of hydrogen and the synthesis of methane and ammonia. The equipment are used to test both structured ceramic/metal catalysts (monoliths, foams, 3D-printed POCS and TPMS) and pellets.

Apparecchiature presenti

  • Laboratory-scale test plant for the study of Autothermal Reforming (ATR), Oxy Steam Reforming (OSR), Tri-Reforming (TR) and Steam Reforming processes for the production of hydrogen from gaseous fuels (methane, propane, biogas). The plant with fixed-bed reactor is suitable for working up to temperatures close to 1000°C, 4 bar maximum pressure, and is equipped with a micro HPLC pump for water dosing and GC analysis and/or online mass spectrometer.
  • Laboratory-scale test plant for the study of Autothermal Reforming (ATR) and Steam Reforming (SR) processes for the production of hydrogen from liquid fuels (diesel). The plant with a fixed bed reactor is suitable for working up to temperatures close to 1000°C, 4 bar maximum pressure, is equipped with two HPLC micro-pumps for dosing water and liquid fuel the system is connected to a GC and/or online mass spectrometer.
  • Laboratory-scale test plant for studying hydrogenation processes (methanation and ammonia synthesis). The plant with a fixed-bed reactor is suitable for working up to temperatures close to 1000°C, 60 bar maximum operating pressure, and is equipped with a micro HPLC pump for water dosing and GC analysis and/or online mass spectrometer.
  • Dual fixed-bed experimental station, high pressure (100 bar) and temperature (1000°C), for continuous catalytic measurements and the possibility of regeneration of the catalytic system under running conditions.
  • DSR 1 – Prototype Syngas Generator designed and built for a maximum hydrogen production of 1.5 Nm3/h, based on the Diesel SR process. aimed at syngas production and/or integration with Solid Oxide Fuel Cell (SOFC) systems for stationary applications. The system is also used for the testing of new reactor configurations and the trial of commercial or developed catalysts on a larger than laboratory scale. The system is equipped with an NDIR analyser for on-line analysis of the produced gases;
  • Bench-scale test facility for the study of Auto-Thermal Reforming (ATR), Oxy Steam Reforming (OSR), Tri-Reforming (TR) and Steam Reforming processes and the study of hydrogenation processes (methanation and ammonia synthesis). The system is used to test new reactor configurations and to trial commercial or developed catalysts on a larger than laboratory scale. The system is equipped with an NDIR analyser for on-line analysis of the produced gases;
  • Optical microscope for 2D and 3D measurements (Keyence), for surface mapping and profilometry measurements even on irregular solid surfaces.
  • Compact modular rheometer (MCR 92, Anton Paar) allowing rheological measurements in both rotational and oscillatory modes.

Partnerships

  • PoliTO – Politecnico di Torino, Dipartimento Scienza Applicata e Tecnologia, Torino (ITALIA)
  • PoliMi – Politecnico di Milano, Dipartimento di Energia, Milano, (ITALIA)
  • PoliMI – Politecnico di Milano, Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Milano (ITALIA)
  • UniME – Università degli Studi di Messina, Dipartimento di Ingegneria, Messina (ITALIA)
  • UniCAL – Università della Calabria, Dipartimento di Ingegneria dell’Ambiente, Rende (ITALIA)
  • UNISA – Università di salerno, Dipartimento di Ingegneria Industriale, Salerno (ITALIA)
  • UNIBO – Università di bologna, Dipartimento di Ingegneria Industriale, Bologna (ITALIA)
  • CNR-ITM – Istituto per la tecnologia delle membrane, Rende (ITALIA)
  • CNR- STEMS – Istituto di Scienze e Tecnologie per l’Energia e la Mobilità Sostenibili, Napoli (ITALIA)
  • TU/e – Eindhoven University of Technology, Department of Chemical Engineering and Chemistry Eindhoven (Olanda)
  • UPC – Universitat Politècnica de Catalunya, Instituto de Técnicas Energéticas , Barcelona, (SPAGNA)
  • UPV – Universitat de Pais Vasco, SUstainable PRocess Engineering, Bilbao (SPAGNA)
  • UOWM- University of Western Macedonia, Department of Chemical Engineering, Western Macedonia (GRECIA).
  • UCT – University of Cape Town, Catalysis Institute, Cape Town, (S. Africa)
  • LU – Lebanese University, Faculty of Science, Beirut (LIBANO)
  • TECNALIA – S. Sebastian (SPAGNA)
  • ENGIE – Courbevoie, (FRANCIA)
  • MERIDIONALE IMPIANTI – Catania (ITALIA)

Immagini dal laboratorio

Personale coinvolto